Azobisisobutyronitrile (AIBN) — CAS 78-67-1
Azobisisobutyronitrile (AIBN) — CAS 78-67-1
Azobisisobutyronitrile (AIBN, CAS 78-67-1) is a widely used azo compound and free-radical initiator, a core process chemical in polymer manufacturing, chemical synthesis, and select industrial applications. UAB An Group Export supplies AIBN in standard and purified grades, matched to each customer's polymerization and processing requirements.
It is used primarily as a free-radical initiator in solution, suspension, and bulk polymerization processes for a wide range of synthetic polymers, and as a chemical blowing agent in select foam manufacturing. Its clean decomposition profile — producing nitrogen gas and isobutyronitrile-derived radicals — makes it a preferred initiator where metallic residues from peroxide initiators are undesirable.
For industrial buyers, supply is coordinated around grade, purity, volume, packaging, and delivery destination, in line with applicable product and transport regulations for self-reactive substances. Bulk and commercial orders are both handled — send your requirements and we'll prepare a quote covering supply, packaging, cold-chain logistics, and delivery.
Key Applications
Polymer ManufacturingA widely used free-radical initiator in solution, suspension, and bulk polymerization of vinyl chloride, styrene, acrylates, methacrylates, and other monomers.
Specialty Coatings & AdhesivesUsed as an initiator in the production of specialty coatings, pressure-sensitive adhesives, and acrylic polymers.
Chemical SynthesisUsed as a radical source in select synthetic chemistry applications requiring a clean, metal-free initiator.
Foam ManufacturingUsed as a chemical blowing agent in select closed-cell foam and expanded polymer manufacturing processes.
Specialty FibersUsed in the production of polyacrylonitrile (PAN) fibers including carbon fiber precursors.
Supply & Packaging
Supplied according to your required grade and purity, quantity, packaging, and destination. Due to its classification as a self-reactive substance (UN 3234, Class 4.1), AIBN is supplied in accordance with dangerous-goods packaging requirements, typically in sealed polyethylene-lined fiber drums or approved containers with specified maximum package quantities per shipment.
Important handling and transport note: AIBN is a thermally unstable, self-reactive solid with an onset decomposition temperature of approximately 65°C and a defined Self-Accelerating Decomposition Temperature (SADT) significantly below that of ambient summer transport conditions in warm climates. It requires refrigerated storage (typically 2–8°C) and cold-chain transport, must be kept strictly away from heat sources, direct sunlight, open flame, and incompatible materials, and is shipped under Class 4.1 self-reactive substance dangerous-goods regulations. Its primary decomposition byproduct, tetramethylsuccinonitrile (TMSN), is acutely toxic — this must be communicated clearly in SDS documentation provided to the buyer. Storage, transport, and handling requirements will be confirmed at the time of quotation based on destination, climate, and shipment duration.
Product Documentation
Available on request, depending on the specific product and supply arrangement:
Safety Data Sheet (SDS), including TMSN decomposition hazard information
Certificate of Analysis (CoA)
Technical Data Sheet (TDS), including SADT and refrigerated storage requirements
Dangerous goods declaration and UN packaging certification
Cold-chain transport documentation
Shipping and transport documentation
Compliance statement:
"Due to the regulated nature of this product, orders are subject to business registration verification and screening against applicable international sanctions and restricted-party lists. Buyers may be required to provide additional end-use declarations, cold-chain storage capability confirmation, or supporting documentation before an order is confirmed. UAB An Group Export reserves the right to decline any order where end use, destination, storage conditions, or buyer information cannot be adequately verified."
Request a Quote
Whether you need AIBN for polymer manufacturing, specialty coatings, chemical synthesis, foam production, or another qualified industrial purpose, provide your requirements and our team will review the available supply options, including cold-chain logistics arrangements where required.
For a quotation, please provide: required grade and purity → quantity → packaging → application → delivery country/city or port → required delivery timeframe → confirmation of refrigerated storage capability at destination

